AFFF Aerospray for Optimax & Firepower Health And Safety Information

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PRODUCT SAFETY DATA SHEET:

Aerospray Without Ethylene Glycol

 

ISSUE NO:

1

 

 

AUTHORISED:

 

 

 

DATE:

October 2002

 

 

 

 

 

 

  • IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE COMPANY UNDERTAKING

Product Name:    

Aerospray Without Ethylene Glycol

 

Application:

Spray Aerowater Fire Fighting

 

  • COMPOSITION/INFORMATION ON THE INGREDIENTS

Ingredients

CAS Number

Synonyms

Concentration %

Health class

Di-ethylene glycol monobutyl ether

112-34-5

2-(2-Butoxyethoxy) ethanol

<10

Xi , R36

Hydrocarbon surfactants

142-31-4

 

<10

Xi , R41,38

Sodium salt

64-17-5

 

<1

R22,36,37,38

Fluorosurfactants

 

 

<5

Xi , R36,37,38

Biocide

 

 

<0.1

Xi, R43

Water

 

Balance

 

  • HAZARDS IDENTIFICATION

Important Hazards

 

 

 

 

Human health hazards: Irritating to eyes, skin and respiratory tract. May cause sensitisation by skin contact

  • FIRST AID MEASURES

First aiders should know and take the precautions appropriate to avoid danger to themselves and the casualty.
Take casualty together with material safety data sheet of this product to hospital or doctor, if necessary

Contact with the Eye

 

Wash out eyes with plenty of water or eye wash solution and seek medical attention.

Contact with the skin

 

Wash off with warm soapy water.  A moisturiser may be used to replenish lost oils.  If persistent irritation occurs, obtain medical attention

Inhalation

 

 

Remove casualty from exposure.  If there is breathing difficulty or cough, keep patient at rest, seated in  position of maximum comfort.

Ingestion

 

 

Send casualty to hospital immediately.  If ingestion is suspected, do not induce vomiting.

  • FIRE FIGHTING MEASURES

 

General Hazards

 

N/A This product is for fire fighting purposes.

  • ACCIDENTAL RELEASE MEASURES

 

Personal precautions

 

Avoid contact with skin, eyes and clothing. Do not breathe mists, aerosols

Personal protection

 

Wear protective clothing specified for normal operations.

Environmental precautions

 

SPILLAGE: The practice of washing spills into drains should be avoided if at all possible and should under no circumstances be allowed without first consulting the local Water Authority and the Environment Agency.

Clean-up methods small spillage

 

Absorb with earth, ash or sawdust for subsequent dry disposal.  Place in a labelled, sealable container for subsequent safe disposal.  Spillages cause slippery floors

  • HANDLING AND STORAGE

 

 

Handling

 

Protect from sustained heat.  Store in original sealed containers or approved systems.  Store in an upright position not more than three high.

Personal Protective Equipment - Fire Fighting

 

The foam concentrates will be used in fire fighting.  This process may involve exposure to heat, flame and possibly toxic vapours and fumes.  We recommend that appropriately designed personal protective equipment designed for use in fire fighting situations should be used

  • EXPOSURE CONTROLS AND PERSONAL PROTECTION

General precautions

 

Use only in well ventilated areas and follow general good housekeeping procedures

Personal Protective Equipment

 

 

Other Handling

 

Avoid prolonged, extensive or repeated inhalation or contact to eyes and skin

Hand Protection

 

Wear impervious gloves of an approved type (e.g. neoprene)

Eye Protection

 

Wear safety goggles of an approved type (BS 2092)

  • PHYSICAL AND CHEMICAL PROPERTIES

Physical state

 

Liquid

Freeze Point

 

-1C

Viscosity at 20oC

 

3.5

pH at 20oC:

 

6-9

Colour

 

Clear pale yellow

Boiling Point

 

100oC at 760 mm Hg

Odour

 

Organic

Flammability

 

Not flammable

Solubility

 

Miscible with water in all proportions

Specific Gravity

 

1.025

  • STABILITY AND REACTIVITY

 

Stability

 

Stable up to 1000C.  Treat as water and exclude from contact with any materials which have violent reactions with water

Hazardous Decomposition Products

 

Do not expose containers to heat or flame, since the containers are made from high density polyethylene and will burn.   Thermal decomposition of containers and/or products may generate acrid smoke and fumes and traces of Na2O,Cl-,SOx,NOx, and HF

  • TOXICOLOGICAL INFORMATION

 

Inhalation

 

Inhalation of hazardous amounts is unlikely when used as intended. Is irritant to respiratory tract when inhaled.

Ingestion

 

Low oral risk when used as intended.  May cause nausea, vomiting and diarrhoea when ingested.

Contact to eyes or skin

 

Low risk if appropriate precaution measures are taken (see section 6).  Can cause skin irritation and damage to the eyes

  • ECOLOGICAL INFORMATION

 

Persistence/degradability

 

Readily biodegradable

Bioaccumulation

 

Bioaccumulation is unlikely to occur due to metabolism and excretion.

Biodegradation

 

 

Biodegradable

 

No data available at present

Ecotoxicity

 

No data available at present

  • DISPOSAL CONSIDERATIONS

 

Disposal of product

 

Waste should be disposed via local authority waste collection service or registered waste carrier.  Ensure the destination is a licensed facility

Local legislation

 

Control of Pollution Act 1974 Environmental Protection Act 1990 Special Waste Regulations 1996

  • TRANSPORT INFORMATION

 

Label for conveyance

 

No Transport Warning Sign Required

Road UN No:

 

N/C

Rail Transport Class No

 

N/C

Sea Transport Class No

 

N/C

MFAG Table No

 

N/C

Air Transport Class No

 

N/C

  • REGULATORY INFORMATION

 

Label For Supply

Irritant

Xi

Risk Phrases

R36, R37, R38, R43

May cause sensitisation to skin and eyes
Irritating to eyes, skin and respiratory tract

Safety Phrases

S23, S24, S25, S26, S29

In case of contact with eyes,             rinse immediately
with plenty of water and seek medical advice.
Wear eye/face protection.
Avoid contact with eyes and skin.
Do not breath vapour/spray

UK Regulatory References

 

Health and Safety at work Act 1974
Chemicals (Hazard Information & Packaging for Supply) Regulations 1994 / Amendment Regulations 1996

EC Directives

 

Substances Directive 67/548/EEC as amended by 69/81/EEC, 70/189/EEC, 73/146/EEC, 75/409/EEC, 79/831/EEC General Preparations Directive 88/379/EEC.

Statutory Instruments

 

Chemicals (Hazard Information and Packaging for Supply) Regulations

Approved Code of Practice

 

Classification and Labelling of Substances and Preparations Dangerous for Supply

Guidance Notes

 

Occupational Exposure Limits EH40/96

  • OTHER INFORMATION

 

 

 

 

AFFF Aerospray for Optimax & Firepower Health And Safety Information

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